Different default printers

Is it possible in Windows XP Professional to set more than one default
printer based on the program being printed from? For instance, I have a user
that prints to one printer for all documents except her Word documents, which
she prints to a separate printer. She would like to know if it's possible to
either set a printer to always print Word documents submitted for printing,
or if Word has the ability to default to a printer other than the Windows
default printer.
Any suggestions/comments would be greatly appreciated!

Thanks,
Somer